Trends & General Reading

What Does Retinol Do? What to Know Before You Start

Trends & General ReadingOp. Dr. Yasemin Aydınlı·9 min read

Short answer: Retinol is the alcohol form of vitamin A and a commonly used member of the retinoid family in cosmetic products. Small studies of specific retinol products have reported an improvement in the appearance of fine wrinkles. This does not mean that every product will have the same effect in every person. Retinol is not a filler, does not restore lost volume and is not an ‘essential’ ingredient that everyone needs to use.[1][2]

A major source of confusion about retinol is treating every molecule in the same family, and every product percentage, as interchangeable. Formulation, stability, delivery system, the amount applied and skin tolerance all affect the outcome. A single conversion chart found online therefore cannot determine which product is suitable for you.

What is retinol and how does it work in the skin?

Retinol is the alcohol form of vitamin A. As a precursor, retinol can be converted in the skin via retinaldehyde into retinoic acid. Retinoic acid binds to receptors in the cell nucleus and regulates how cells function. This does not mean that it changes the genetic code of DNA.[4][5]

Topical retinoids may affect epidermal cell behaviour, pigment distribution and collagen-related pathways. However, this mechanistic evidence does not prove that every over-the-counter retinol product will produce the same clinical result for facial tone, texture or wrinkles.[4]

What is the difference between retinyl palmitate, retinol, retinal and tretinoin?

IngredientMain characteristicWhat to know
Retinyl palmitateIt is the palmitic acid ester of retinol; it is not the same molecule as retinol.Esterases can convert it to retinol, then to retinal and retinoic acid. These three conversion steps do not automatically make it the weakest or safest option in every formulation; its percentages are not equivalent to those of other retinoids.
RetinolA form of vitamin A found in cosmetic products.It acts after conversion to retinaldehyde and retinoic acid; products may not be equivalent even when they state the same percentage.
Retinal (retinaldehyde)The intermediate form between retinol and retinoic acid.It is converted into retinoic acid in the skin. Claims that it is always a fixed number of times stronger than retinol cannot be applied to every formulation.
Tretinoin (retinoic acid)The directly active, prescription medicine form.It cannot be compared directly with a retinol percentage; its benefits and risk of irritation should be assessed under medical supervision.[3]

Retinyl palmitate is a retinoid ester used in cosmetic products. This ester of retinol and palmitic acid can be broken down into retinol by skin esterases, after which it may follow the pathway to retinal and retinoic acid. This additional step does not mean that it is necessarily weaker or less irritating in every product. A product containing retinyl palmitate should not be assumed to be inherently safe during pregnancy or breastfeeding.[6]

Other cosmetic forms, such as retinyl esters, also exist. Although a molecule’s conversion pathway matters, fewer steps do not always mean a better product. Packaging, exposure to light and air, the other ingredients in the product and whether it can be used consistently also matter.

Product classification, permitted concentrations and prescription requirements may vary by country. Follow the label, official rules where you live and your healthcare professional’s advice.

How retinol is converted

Retinyl palmitateThe palmitic acid ester of retinol
Esterase enzymes
RetinolThe alcohol form of vitamin A
RDH enzymes
RetinalRetinaldehyde
RALDH / ALDH enzymes
Retinoic acidTretinoin
This is a schematic biology illustration; it does not show a patient image or a procedure outcome. Esterase enzymes can split retinyl palmitate into retinol. RDH (retinol dehydrogenase) enzymes convert retinol to retinal. RALDH / ALDH (retinaldehyde dehydrogenase) enzymes enable the conversion of retinal to retinoic acid. Retinal can also be converted back to retinol. Not all storage and breakdown pathways are shown; the number of steps alone does not determine a product’s potency.[5][6]
Results of every surgical or interventional procedure may vary from person to person. You are advised to obtain detailed information from your doctor before the procedure.

What does the evidence say about the benefits of retinol?

The evidence is promising but limited. In a 2007 study by Kafi and colleagues, 0.4% retinol was applied to one arm of 36 older adults, with a modest improvement in fine wrinkles reported after 24 weeks. This does not prove that the same effect applies to every concentration, every facial product or every age group.[1] In a separate 12-week facial application in the study by Kong and colleagues, a specific 0.1% retinol product was associated with reduced wrinkle measurements in 41 women. This part of the study was not a facial comparison with retinoic acid; the results cannot be generalised to all products.[2]

These studies reported a limited change seen over weeks and months under specific study conditions, not rapid ‘rejuvenation’. A cream should not be expected to eliminate deep expression lines, sagging or volume loss.[1][2]

What happens in the cell after conversion?

Retinoic acidSignals to the cell
Nuclear receptorsRAR / RXR complex
Regulation of gene activityCellular response
This is a schematic biology illustration; it does not show a patient image or a procedure outcome. This second diagram summarises the intracellular signalling pathway rather than enzymatic conversion. Retinoic acid regulates the activity of certain genes through the RAR / RXR receptor complex; it does not alter the genetic code of DNA. This mechanism does not mean that every product will produce the same clinical outcome in everyone.[4][5]
Results of every surgical or interventional procedure may vary from person to person. You are advised to obtain detailed information from your doctor before the procedure.

How should you start using retinol?

There is no rigid ‘1-2-3 rule’ that suits everyone. The product instructions, the current condition of your skin and any other treatments affect the starting plan. A general approach is to apply a small amount to clean, completely dry skin, avoiding the eye and lip margins; start infrequently and increase only if the skin tolerates it. Working up to nightly use is not a measure of success.

Using moisturiser before and/or after retinol may reduce dryness for some people. This ‘sandwich’ method is optional and cannot be guaranteed to prevent irritation completely. If you use exfoliating acids, benzoyl peroxide or other irritants on the same evening, you may need to separate them according to the product instructions or your doctor’s advice. Retinol and vitamin C are not inherently incompatible; tolerance when using them together varies from person to person.

Irritation or an acne flare (‘purging’)?

Not every worsening after starting retinol should be called ‘purging’. Acne lesions and irritation are not the same; consult a doctor if the distinction is unclear. Widespread redness, marked itching, burning, cracking or eczema around the eyes may indicate irritation or a contact reaction. Irritation is not proof that the product is working. Continuing regardless may further damage the skin barrier.

When should you take a break? Stop the product and seek advice from a healthcare professional if you develop severe burning, swelling, blistering, pain or persistent eczema. For milder dryness, reducing the frequency and using a gentle cleanser and simple moisturiser may help. Do not restart before the symptoms have resolved.

Can retinol be used around the eyes?

The eye area is more sensitive. Do not apply a regular facial product to the eyelids or lash line on the assumption that retinol will necessarily ‘thicken’ this area. Use only a product designed for the eye area, following its instructions and, when needed, medical advice. If the product gets into the eye, rinse with plenty of water; seek medical care for persistent burning or visual symptoms.

Can retinol be used in summer, and what sun protection is needed?

Retinol is not automatically ruled out simply because it is summer; however, irritation and superficial peeling may make the skin more vulnerable to the effects of the sun. Use the product at night. During the day, apply a broad-spectrum SPF 30 or higher sunscreen in a sufficient amount and reapply as needed; also include shade, a hat and protective clothing in your plan. No sunscreen makes prolonged, intense sun exposure completely safe.

Retinol during pregnancy and breastfeeding

Oral retinoids are well known to carry a risk of serious birth defects during pregnancy. Systemic absorption from topical products is much lower and harm to the fetus is considered unlikely; nevertheless, as a precaution the European Medicines Agency recommends that topical retinoid medicines should not be used during pregnancy or when planning a pregnancy. The American Academy of Dermatology also advises avoiding over-the-counter products containing retinol during pregnancy. If you are planning to become pregnant, discuss when to stop the product with your own doctor.[7][8]

During breastfeeding, direct contact between the baby and the product must be considered as well as transfer into breast milk. Application areas away from the breast, such as the face, neck or hands, may still touch the baby’s skin or mouth. It may therefore be prudent to postpone cosmetic retinoid use until after breastfeeding. If treatment is needed, the decision should be made with a doctor.

LactMed states that topical tretinoin is considered a low risk to a breastfed infant because absorption through the skin is low, but it has not been studied directly during breastfeeding. This does not mean that all over-the-counter retinol, retinal or retinyl palmitate products are safe. Keep treated areas away from the baby’s skin and mouth; do not apply to the breast, nipple or areola, and wash your hands after application.[9]

There is also insufficient evidence to establish that bakuchiol, marketed as ‘plant-based’, is safe during pregnancy.

Who should consult a doctor first?

People with eczema, rosacea, active dermatitis, significant barrier damage or persistent acne; those using prescription acne treatment; and those who have recently had laser treatment, a peel or a similar procedure should not start the product on their own. Retinol is not a substitute for treatment of a skin condition. The appropriate product and frequency may vary according to your diagnosis and the other steps in your skincare routine.

Result

Some effects of retinol have been examined in clinical studies. Retinol is not a miracle, a filler or an essential prescription for everyone. The best approach is not to seek the highest percentage, but to use a suitable product that your skin tolerates, consistently and patiently. Peeling is not the goal. Daily sun protection, a simple routine and medical assessment when needed are as important as retinol itself.

This article provides general information and is not a diagnosis or personalised treatment advice. If you have a skin condition, are planning a pregnancy or receive regular treatment, assess the product together with your doctor.

Last updated: 20 September 2026 · Editor contact: [email protected]

Frequently Asked Questions

Does retinol thin the skin?

Superficial peeling caused by retinoids does not mean that the skin has become permanently thinner. However, redness, burning and dryness may indicate irritation of the skin barrier; severe symptoms should not be considered normal.

Can retinol be used in summer?

Some people can use it in summer, but irritated skin is more vulnerable to the sun. Night-time application, broad-spectrum SPF 30 or higher during the day, shade and protective clothing are important.

How long does retinol take to work?

Clinical studies of specific products have reported changes after 12–24 weeks. The timeframe varies with the formulation, pattern of use, skin and the concern being addressed; definite results should not be expected within a few weeks.

Should retinol be used every night?

No. Nightly use is neither necessary nor tolerable for everyone. It is more appropriate to start infrequently and increase only as tolerated, guided by the product instructions, your skin’s response and medical advice when needed.

Can retinol be applied around the eyes?

It should not be applied indiscriminately to the eyelids or lash line. Use only a product designed for the eye area, according to its instructions and with medical advice if needed; rinse with plenty of water if it gets into the eye.

Can retinol be used during pregnancy or breastfeeding?

Topical retinoid medicines and over-the-counter retinol products should be avoided during pregnancy. During breastfeeding, both systemic absorption and the baby’s direct contact with the application area should be considered. Postponing cosmetic use may be prudent; if treatment is needed, decide with a doctor, do not apply to the breast or areas that touch the baby, and wash your hands.

References

  1. Kafi R, Kwak HS, Schumacher WE, et al. Improvement of naturally aged skin with vitamin A (retinol). Arch Dermatol. 2007;143(5):606–612. DOI: 10.1001/archderm.143.5.606. PMID 17515510
  2. Kong R, Cui Y, Fisher GJ, Wang X, Chen Y, Schneider LM, Majmudar G. A comparative study of the effects of retinol and retinoic acid on histological, molecular, and clinical properties of human skin. J Cosmet Dermatol. 2016;15(1):49–57. DOI: 10.1111/jocd.12193. PMID 26578346
  3. Griffiths CEM, Kang S, Ellis CN, et al. Two concentrations of topical tretinoin (retinoic acid) cause similar improvement of photoaging but different degrees of irritation: A double-blind, vehicle-controlled comparison of 0.1% and 0.025% tretinoin creams. Arch Dermatol. 1995;131(9):1037–1044. DOI: 10.1001/archderm.1995.01690210067011. PMID 7544967
  4. Motamedi M, Chehade A, Sanghera R, Grewal P. A Clinician's Guide to Topical Retinoids. J Cutan Med Surg. 2022;26(1):71–78. DOI: 10.1177/12034754211035091. PMID 34292058
  5. Kedishvili NY. Retinoic Acid Synthesis and Degradation. Subcell Biochem. 2016;81:127–161. DOI: 10.1007/978-94-024-0945-1_5. PMID 27830503
  6. Boehnlein J, Sakr A, Lichtin JL, Bronaugh RL. Characterization of esterase and alcohol dehydrogenase activity in skin. Metabolism of retinyl palmitate to retinol (vitamin A) during percutaneous absorption. Pharm Res. 1994;11(8):1155–1159. DOI: 10.1023/A:1018941016563. PMID 7971717
  7. American Academy of Dermatology. Retinoid or retinol? and Pregnancy skin care.
  8. European Medicines Agency. Updated measures for pregnancy prevention during retinoid use.
  9. National Library of Medicine, LactMed. Tretinoin. Updated 15 October 2024.